Heads up! This post was written 11 years ago. Some information might be outdated or may have changed since then.
If you want to disable this annoying ads in new version of Skype you can add this line 
public class Main {
    public static void main(String[] args) {
        System.out.println("127.0.0.1");
        System.out.println("apps.skype.com");
    }
}

in your host file, which are usualy located in 
%systemroot%\system32\drivers\etc\hosts

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